Vash the Stampede

Moveset
Special 1: Warning Shot

Special 2: Hair's Breadth Shot

Special 3: Deadly Dodge

Special 4: Bubble Gum

R3 Form Change: Serious Mode

Moveset (Serious Mode)
Special 1: Piercing Shot

Special 2: Black Hole Shot

Special 3: Hidden Machine Gun

Form Change: Angel Wings

R3 Ultimate: Angel Cannon

Warning Shot
First Appearance: Episode 7

Mash the special button to fire near the opponent's legs. If they move forward, they'll get hit.

Hair's Breadth Shot
First Appearance: Episode 10

Press the special button to fire a bullet that cuts the enemy's cheek.

Bullet Eject

First Appearance: Episode 4

Next, press the special button to fling bullets from your gun cylinder into the enemy's face.

No Ammo

First Appearance: Episode 1

Finally, press the special button to throw your gun into the enemy's face. You then jump forward to retrieve it.

Deadly Dodge
First Appearance: Episode 1

Press the special button to act scared. If hit, you roll out of the way while simultaneously kicking the projectile back at the enemy.

Shoe Knife

First Appearance: Episode 3

When used in close range, you kick the enemy with your hidden shoe knife.

Bubble Gum
First Appearance: Episode 4

Mash the special button to chew bubble gum. Hold the button to blow a bubble, and release to pop it. Stuns the enemy.

Piercing Shot
First Appearance: Episode 24

Press the special button to fire a bullet that goes through the enemy.

Black Hole Shot
Press the special button to fire a bullet that creates a miniature black hole. It absorbs projectiles and sucks in foes.

Hidden Machine Gun
First Appearance: Episode 12

Mash the special button to fire bullets from your machine gun arm.

Backhand Machine Gun

First Appearance: Episode 15

If hit, you appear in front of enemy with your back facing them, and fire without looking.

Angel Cannon
First Appearance: Episode 16

Press the special button to fuse your gun with your hand, creating a gigantic angel arm. You fire an uncontrollable beam that vaporizes the enemy.